Halogenation reactions of a ditelluride having bulky aryl groups leading to the formation of organotellurium halides
作者： Takahiro Sasamori , Koh Sugamata , Norihiro Tokitoh
DOI: 10.1002/HC.20698
关键词: Heteroatom 、 Halide 、 General chemistry 、 Organic chemistry 、 Halogenation 、 Chemistry 、 Reagent 、 Medicinal chemistry 、 Tellurium 、 Trimethylsilyl 、 Aryl
摘要: Halogenation reactions of BbtTe-TeBbt (Bbt; 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris (trimethylsilyl)methyl]phenyl) with SO2Cl2, Br2, and I2 were examined. When 1 equiv the reagents used, corresponding tellurium monohalides obtained as stable crystalline compounds. Although iodination reaction using 3 afforded BbtTeI, treatment SO2Cl2 Br2 gave trihalides, BbtTeX3(X = Cl, Br), Characterization mono- trihalides was achieved by spectroscopic crystallographic analyses, together theoretical calculations. © 2011 Wiley Periodicals, Inc. Heteroatom Chem 22:405–411, 2011; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.20698
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