Trip2C6H3SeF: the first isolated selenenyl fluoride.
作者： Helmut Poleschner , Stefan Ellrodt , Moritz Malischewski , Jun-ya Nakatsuji , Christian Rohner
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摘要: Joining the stable: The first examples of highly instable selenenyl fluorides RSeF are prepared from reaction on tin selenide RSeSnMe(3) with XeF(2). Through use extremely large protecting groups (m-terphenyl ligands) which stabilizes units against disproportionation, compounds could be isolated and characterized by NMR spectroscopy single-crystal structure analysis (see structure).
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