C2-Symmetric Ni(II) α-Diimines Featuring Cumyl-Derived Ligands: Synthesis of Improved Elastomeric Regioblock Polypropylenes
作者： Jeffrey M. Rose , Fanny Deplace , Nathaniel A. Lynd , Zhigang Wang , Atsushi Hotta
DOI: 10.1021/MA8019943
关键词: Elastomer 、 Stereospecificity 、 Aniline 、 Schiff base 、 Polymerization 、 Chemical synthesis 、 Polymer chemistry 、 Crystal structure 、 Nickel 、 Chemistry
摘要: A series of chiral, nickel α-diimine complexes featuring ligands based on bulky cumyl-substituted aniline moieties was synthesized. Each complex capable polymerizing propylene upon activatio...
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