Raman spectroscopy of the joaquinite minerals
作者： Ray L. Frost , Caroline Pinto
DOI: 10.1002/JRS.1711
关键词: Infrared 、 Diffraction 、 Silicate 、 Chemistry 、 Group (periodic table) 、 Analytical chemistry 、 Mineral 、 Raman spectroscopy
摘要: Selected joaquinite minerals have been studied by Raman spectroscopy. The are categorised into two groups depending upon whether bands occur in the 3250 to 3450 cm−1 region and 3600 region, or latter only. first set of is attributed water stretching vibrations second OH bands. In literature, X-ray diffraction could not identify presence units structure joaquinite. spectroscopy proves that mineral group contains their structure, some cases both units. A series at 1123, 1062, 1031, 971, 912 892 assigned SiO vibrations. Bands above 1000 attributable νas modes (SiO4)4− (Si2O7)6− observed 738, around 700, 682 668, 621 602 OSiO bending modes. patterns do appear match published infrared spectral either reason actual formulation mineral, which significant amounts Ti Nb Fe found. Copyright © 2007 John Wiley & Sons, Ltd.
core.ac.uk
sci-hub.se 参考文章(8)
George R. Rossman, Joaquinite: The Nature of its Water Content and theQuestion of Four-Coordinated Ferrous Iron American Mineralogist. ,vol. 60, pp. 435- 440 ,(1975)
George R Rossman, Michael N Taran, None, Spectroscopic standards for four- and fivefold-coordinated Fe2+ in oxygen-based minerals American Mineralogist. ,vol. 86, pp. 896- 903 ,(2001) , 10.2138/AM-2001-0713
Ray L Frost, Onuma Carmody, Kristy L Erickson, Matt L Weier, Jir̆ı́ C̆ejka, Molecular structure of the uranyl mineral andersonite—a Raman spectroscopic study Journal of Molecular Structure. ,vol. 703, pp. 47- 54 ,(2004) , 10.1016/J.MOLSTRUC.2004.06.001
Ray L. Frost, An infrared and Raman spectroscopic study of the uranyl micas. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 60, pp. 1469- 1480 ,(2004) , 10.1016/J.SAA.2003.08.013
Ray L. Frost, Dermot A. Henry, Kristy Erickson, Raman spectroscopic detection of wyartite in the presence of rabejacite Journal of Raman Spectroscopy. ,vol. 35, pp. 255- 260 ,(2004) , 10.1002/JRS.1144
E. Cannillo, F. Mazzi, G. Rossi, The structure type of Joaquinite TMPM Tschermaks Mineralogische und Petrographische Mitteilungen. ,vol. 17, pp. 233- 246 ,(1972) , 10.1007/BF01082804
Arden L. Albee, Jo Laird, Chemical composition and physical, optical, and structural properties of benitoite, neptunite, and joaquinite American Mineralogist. ,vol. 57, pp. 85- 102 ,(1972)
H. Sørensen, E. I. Semenov, V. I. Bukin, Yu. A. Balashov, Rare Earths in Minerals of the Joaquinite Group American Mineralogist. ,vol. 52, pp. 1762- 1769 ,(1967)