Friedel-Crafts reactions of some vinylsilanes
作者： Ian Flaming , Andrew Pearce
DOI: 10.1039/P19800002485
关键词: Friedel–Crafts reaction 、 Trimethylsilyl 、 Silanes 、 Organic chemistry 、 Styrene 、 Chloride 、 Benzoyl chloride 、 Chemistry 、 Medicinal chemistry 、 Carbon atom
摘要: Substituted cyclohexenylsilanes (2), (5), (9), and (13) undergo Friedel–Crafts reactions to give substitution products, site-selectively at the carbon atom carrying trimethylsilyl group. β-Trimethylsilylstyrene (17) similarly gives more in with benzoyl chloride phenylacetyl than styrene itself. The syntheses of silanes are reported, some limitations idea identified.
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