The temperature dependence of chemical shielding in diatomic molecules: CO, F2, ClF, HBr, and HCl

作者: A. Keith Jameson , Karla Schuett , Cynthia J. Jameson , Sheila M. Cohen , Harriet Parker

DOI: 10.1063/1.435147

关键词: Chemical shieldingVirial expansionDiatomic moleculePhysical chemistryChemistryMolecular physics

摘要: The temperature dependence of chemical shielding in CO, F2, ClF, HBr, and HCl gas has been measured. functions σ0(T) σ1(T) the virial expansion σ =σ0(T)+σ1(T) ρ+⋅⋅⋅ are reported here for 13C, 19F, 1H nuclei. largest shifts with observed F2.

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