Vibrational Motion in the Regular and Chaotic Regimes, Classical and Quantum Mechanics

摘要: There are many experiments which related to intramolecular energy transfer. Initially, they involved primarily thermal unimolecular reactions1 and chemical activation.2 More recently, more state-selective have also been performed in one zeroth order mode (e.g., some bond or normal mode) has excited. These include infrared multiphoton absorption,3 reactions induced by excitation of high CH overtones,4 dissociation vibrational state-excited van der Waals’ complexes,5 fluorescence spectra from mode-selected vibrationally-excited substituted aromatic molecules.6