Crystalline insoluble acid salts of tetravalent metals—XXXIV
作者： G. Alberti , M.G. Bernasconi , M. Casciola , U. Costantino
DOI: 10.1016/0022-1902(80)80329-0
关键词: Ion 、 Chemistry 、 Aqueous solution 、 Ion exchange 、 Ammonium 、 Ammonia 、 Inorganic chemistry 、 Phosphate 、 Potassium 、 Hydrogen 、 Materials Chemistry 、 Polymers and Plastics
摘要: Abstract The H + NH 4 ion-exchange and the ammonia uptake on γ-Ti(HPO4)2·2H2O has been investigated. first proton (3.63 meq/g) is completely exchanged at pH 7, without appreciable change in inter-layer distance. From 80 to 100% of exchange, there is, instead, a discontinuous from 11.2 13.6 A phase γ-Ti(NH4PO4)2 · NH2O formed. Also taken up, high rate, aqueous solution with formation half-and fully NH4+ forms. Thus use γ-titanium phosphate removal NH3 or ions waste solution, kidney machines, seems be possible. study potassium ammonium forms showed that structure layers phosphate, as already found for α-zirconium does not appreciably during an process.
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sci-hub.se 参考文章(10)
G. Alberti, R. Bertrami, U. Costantino, J.P. Gupta, Crystalline insoluble acid salts of tetravalent metals—XXVI Journal of Inorganic and Nuclear Chemistry. ,vol. 39, pp. 1057- 1060 ,(1977) , 10.1016/0022-1902(77)80263-7
Giulio Alberti, Umberto Constantino, Recent progress in the field of synthetic inorganic exchangers having a layered or fibrous structure Journal of Chromatography A. ,vol. 102, pp. 5- 29 ,(1974) , 10.1016/S0021-9673(01)85423-6
Shoji Yamanaka, Structural Consideration of Zirconium Phosphate and its Organic Complexes Clays and Clay Minerals. ,vol. 23, pp. 477- 478 ,(1975) , 10.1346/CCMN.1975.0230613
G. Alberti, P. Cardini-Galli, U. Costantino, E. Torracca, Crystalline insoluble salts of polybasic metals—I Ion-exchange properties of crystalline titanium phosphate Journal of Inorganic and Nuclear Chemistry. ,vol. 29, pp. 571- 578 ,(1967) , 10.1016/0022-1902(67)80063-0
M.A. Awwal, D.J. Carswell, Extraction of thorium by secondary amines Journal of Inorganic and Nuclear Chemistry. ,vol. 30, pp. 1057- 1063 ,(1968) , 10.1016/0022-1902(68)80325-2
Dietmar Behrendt, Klaus Beneke, Gerhard Lagaly, Intercalation Compounds of Zirconium Phosphate Angewandte Chemie. ,vol. 15, pp. 544- 545 ,(1976) , 10.1002/ANIE.197605441
Shoji Yamanaka, Masami Tanaka, Formation region and structural model of γ-zirconium phosphate Journal of Inorganic and Nuclear Chemistry. ,vol. 41, pp. 45- 48 ,(1979) , 10.1016/0022-1902(79)80391-7
G. Alberti, U. Constantino, M.L. Luciani Giovagnotti, Crystalline insoluble acid salts of tetravalent metals—XXVIII synthesis of crystalline Ti(HPO4)2·2H2O by the HF procedure and some comments on its formation and structure Journal of Inorganic and Nuclear Chemistry. ,vol. 41, pp. 643- 647 ,(1979) , 10.1016/0022-1902(79)80348-6
V Veselý, Synthetic inorganic ion-exchangers—I Hydrous oxides and acidic salts of multivalent metals Talanta. ,vol. 19, pp. 219- 262 ,(1972) , 10.1016/0039-9140(72)80075-4
Giulio Alberti, Syntheses, crystalline structure, and ion-exchange properties of insoluble acid salts of tetravalent metals and their salt forms ChemInform. ,vol. 9, pp. 163- 170 ,(1978) , 10.1021/AR50124A007