Lamellar inorganic ion exchangers Li+Cs+H+ ion exchange in γ-titanium phosphate
作者： Camino Trobajo , Ricardo Llavona , Julio Rodríguez
DOI: 10.1016/0025-5408(91)90010-J
关键词:
摘要: An equilibrium study of the Na+Cs+H+ ion exchange on γ-titanium phosphate has been carried out. Isotherms for have determined and phases formed during identified. Over entire composition range, exchanger greatly prefers cesium to sodium. For 0–25% exchange, sodium 25% conversion were found be at when ratio sodium-cesium concentration solution is 100:1. The constant determined. When 50% reached by addition stoichiometric amount base, a solid barHNaxCs1−x formula (with varying with composition) formed. substitution process Na+Cs+ in phase A diagram ternary system given. results are compared those previously obtained Na+H+ Cs+H+ binary systems. mechanism proposed.
elsevier.com
sci-hub.se 参考文章(28)
Lennart Kullberg;, Abraham Clearfield, ON THE MECHANISM OF ION EXCHANGE IN ZIRCONIUM PHOSPHATES XXXIII. AN EQUILIBRIUM STUDY OF Na+-K+-H+ EXCHANGE ON CRYSTALLINE α-ZIRCONIUM PHOSPHATE Solvent Extraction and Ion Exchange. ,vol. 1, pp. 77- 96 ,(1983) , 10.1080/07366298308918393
R. Llavona, J.R. García, M. Suárez, J. Rodríguez, Thermodynamic treatment of H+/K+ ion-exchange on γ-titanium phosphate Thermochimica Acta. ,vol. 101, pp. 101- 105 ,(1986) , 10.1016/0040-6031(86)80045-4
Celia Alvarez, Ricardo Llavona, José R. García, Marta Suárez, Julio Rodríguez, Lamellar inorganic ion exchangers. Proton–copper(II) ion exchange in γ-titanium bis(hydrogenphosphate) J. Chem. Soc., Dalton Trans.. pp. 2045- 2050 ,(1987) , 10.1039/DT9870002045
Celia Alvarez, Ricardo Llavona, JoséR. García, Marta Suárez, Julio Rodríguez, X-ray diffraction spectrometry in lamellar ion-exchangers for the analysis of the substitution phases with thermal splitting Materials Research Bulletin. ,vol. 23, pp. 487- 495 ,(1988) , 10.1016/0025-5408(88)90155-9
Celia Alvarez, Ricardo Llavona, Jose R. Garcia, Marta Suarez, Julio Rodriguez, Lamellar inorganic ion exchangers. Hydrogen(1+)/calcium(2+) ion exchange in .gamma.-titanium phosphate Inorganic Chemistry. ,vol. 26, pp. 1045- 1049 ,(1987) , 10.1021/IC00254A016
O. B. Michelsen, Photometric Determination of Phosphorus as Molybdovanadophosphoric Acid Analytical Chemistry. ,vol. 29, pp. 60- 62 ,(1957) , 10.1021/AC60121A017
M. Suarez, J. R. Garcia, J. Rodriguez, Thermodynamic treatment of proton/sodium(1+) ion exchange on .alpha.-titanium phosphate The Journal of Physical Chemistry. ,vol. 88, pp. 159- 162 ,(1984) , 10.1021/J150645A036
Shoji Yamanaka, Masami Tanaka, Formation region and structural model of γ-zirconium phosphate Journal of Inorganic and Nuclear Chemistry. ,vol. 41, pp. 45- 48 ,(1979) , 10.1016/0022-1902(79)80391-7
S. Allulli, C. Ferragina, A. La Ginestra, M.A. Massucci, N. Tomassini, Preparation and ion-exchange properties of a new phase of the crystalline titanium phosphate, Ti(HPO4)2·2H2O Journal of Inorganic and Nuclear Chemistry. ,vol. 39, pp. 1043- 1048 ,(1977) , 10.1016/0022-1902(77)80261-3
Eliana González, Ricardo Llavona, José R. Garcia, Julio Rodríguez, Lamellar inorganic ion exchangers. H+/Cs+ ion exchange in γ-titanium phosphate Journal of The Chemical Society-dalton Transactions. pp. 1825- 1829 ,(1989) , 10.1039/DT9890001825