Thermodynamic treatment of H+/K+ ion-exchange on γ-titanium phosphate
作者： R. Llavona , J.R. García , M. Suárez , J. Rodríguez
DOI: 10.1016/0040-6031(86)80045-4
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摘要: Abstract The H + /K ion-exchange process in γ-Ti(HPO 4 ) 2 ·2H O was studied, titration and hydrolysis curves exchange isotherms being obtained at 278.15, 298.15, 313.15 328.15 (±0.1) K. Three differentiated processes of substitution crystalline phases 25, 50 100% conversion were reached. equilibrium constants, the standard molar Gibbs free energies, enthalpies entropies reaction determined.
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