作者: Roger Marchand
DOI: 10.1016/S0168-1273(98)25005-7
关键词: Ternary operation 、 Carbon 、 Crystallography 、 Chemical bond 、 Ionic bonding 、 Carbide 、 Chemistry 、 Metal 、 Nitride 、 Nitrogen 、 Inorganic chemistry
摘要: Publisher Summary This chapter reviews ternary and higher order nitride materials. Such multinary materials result from association to rare-earth metal nitrogen of other elements, which can belong either the cationic or anionic subnetwork. Considering R–M–N nitrides, where M is a element, different categories compounds are found depending on M, more precisely nature M–N chemical bond. It well-known that nitrogen, located in Periodic Table between carbon oxygen, gives rise two main classes binary nitrides having similarities with carbides oxides. Transition thus, closely related transition essentially metallic character, because they be generally described as insertion network. Iono-covalent less significant ionic covalent form second class compounds—close oxides—that includes nitrides.