Solid-Phase Synthesis and Encoding Strategies for Olefin Polymerization Catalyst Libraries

作者: Thomas R. Boussie , Carla Coutard , Howard Turner , Vince Murphy , Timothy S. Powers

DOI: 10.1002/(SICI)1521-3773(19981217)37:23<3272::AID-ANIE3272>3.0.CO;2-R

关键词: Polymer chemistrySolid-phase synthesisNickelCatalysisPolymerPalladiumCombinatorial chemistryCleavage (embryo)DiimineHeterogeneous catalysisChemistryGeneral chemistry

摘要: Active polymerization catalysts, novel resin-bound diimine complexes of nickel(II) and palladium(II) are obtained by combinatorial synthesis combined in a catalyst library. By tagging with fluorescent markers, the catalysts can be coded. Therefore, after cleavage tag from polymer-coated resin, HPLC used to determine pathway along which products were formed.

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