Dependence of Energy Gap onxin CuAlxGa1-xS2Mixed Crystal System

作者: Nozomu Tsuboi , Satoshi Kobayashi , Futao Kaneko , Takeo Maruyama

DOI: 10.1143/JJAP.27.972

关键词: Single crystalExcitonValence (chemistry)Absorption spectroscopyBand gapMolecular physicsOpticsElectronic band structureEnergy level splittingCrystal field theoryChemistryGeneral EngineeringGeneral Physics and Astronomy

摘要: The transmission and reflectance spectra for various x in CuAlxGa1-xS2 single crystals have been measured with polarized light. photon energies of excitons associated the uppermost valence bands are determined by analyzing exciton absorption anomaly at room temperature about 80 K. an approximately quadratic dependence x. band splitting is predominantly due to crystal field splitting. energy varies almost linearly

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