3-D polymeric structure formed by hydrogen bonds of copper (II) complex

作者: Elif Gungor

DOI: 10.1080/15421406.2016.1262169

关键词: Hydrogen bondCopperClose contactIonHydrogenAromaticityDiffractionChemistryCrystal structureCrystallography

摘要: ABSTRACTA new copper complex trans-Dichlorobis[4-methoxypyridine]copper(II) (1) was synthesized and its crystal structure determined by X-ray diffraction. The close Cu···Cl contacts between the molecular units form bi-bridged dimers. Copper(II) ion completes 4 + 2 coordination via interaction with contact. has a polymeric of infinite one-dimensional (1D) chains, consisting six-coordinate copper(II) units. C–H···C l intermolecular connect 1D-chains in 1 which to 3D structure. π ··· interactions aromatic rings are also observed hydrogen bonded assembly 1.

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