Structural and Optical Properties of Spray-deposited Cu2ZnSnS4 thin Films
作者： R.J. Deokate , A.D. Adsool , N.S. Shinde , S.M. Pawar , C.D. Lokhande
DOI: 10.1016/J.EGYPRO.2014.07.304
关键词: Phase (matter) 、 Thin film 、 Band gap 、 Materials science 、 CZTS 、 Diffraction 、 Scanning electron microscope 、 Kesterite 、 Analytical chemistry 、 Energy Dispersive Spectrometer
摘要: Abstract Stoichiometric kesterite Cu2ZnSnS4 (CZTS) thin films were successfully synthesized by spray pyrolysis on heated glass under the air atmosphere. The characterization of its structure, morphology, phase constituents, and optical properties done using powder X-ray diffraction (XRD), Scanning electron microscope (SEM), Energy Dispersive Spectrometer (EDS) ultraviolet–visible (UV–vis) spectrophotometry, respectively. showed single with a structure. composition CZTS film was basically corresponds theoretical value. Moreover, prepared products morphology size ranging from 200–400 nm.The observed bandgap 1.5 eV matched well bulk material which made them promising candidates as absorber materials for photovoltaic applications.
core.ac.uk
elsevier.com
sci-hub.se 参考文章(36)
Kunihiko Tanaka, Masatoshi Oonuki, Noriko Moritake, Hisao Uchiki, Cu2ZnSnS4 thin film solar cells prepared by non-vacuum processing Solar Energy Materials and Solar Cells. ,vol. 93, pp. 583- 587 ,(2009) , 10.1016/J.SOLMAT.2008.12.009
Kentaro Ito, Tatsuo Nakazawa, Electrical and Optical Properties of Stannite-Type Quaternary Semiconductor Thin Films Japanese Journal of Applied Physics. ,vol. 27, pp. 2094- 2097 ,(1988) , 10.1143/JJAP.27.2094
Christine Chory, Folker Zutz, Florian Witt, Holger Borchert, Jürgen Parisi, Synthesis and characterization of Cu2ZnSnS4 Physica Status Solidi (c). ,vol. 7, pp. 1486- 1488 ,(2010) , 10.1002/PSSC.200983217
Y.B. Kishore Kumar, G. Suresh Babu, P. Uday Bhaskar, V. Sundara Raja, Preparation and characterization of spray-deposited Cu2ZnSnS4 thin films Solar Energy Materials and Solar Cells. ,vol. 93, pp. 1230- 1237 ,(2009) , 10.1016/J.SOLMAT.2009.01.011
Kunihiko Tanaka, Noriko Moritake, Hisao Uchiki, Preparation of Cu2ZnSnS4 thin films by sulfurizing sol–gel deposited precursors Solar Energy Materials and Solar Cells. ,vol. 91, pp. 1199- 1201 ,(2007) , 10.1016/J.SOLMAT.2007.04.012
Jonathan J. Scragg, Philip J. Dale, Laurence M. Peter, Guillaume Zoppi, Ian Forbes, New routes to sustainable photovoltaics: evaluation of Cu2ZnSnS4 as an alternative absorber material Physica Status Solidi B-basic Solid State Physics. ,vol. 245, pp. 1772- 1778 ,(2008) , 10.1002/PSSB.200879539
C. Domain, S. Laribi, S. Taunier, J.F. Guillemoles, Ab initio calculation of intrinsic point defects in CuInSe2 Journal of Physics and Chemistry of Solids. ,vol. 64, pp. 1657- 1663 ,(2003) , 10.1016/S0022-3697(03)00208-7
Karthik Ramasamy, Mohammad A Malik, Paul O'Brien, None, The chemical vapor deposition of Cu2ZnSnS4 thin films Chemical Science. ,vol. 2, pp. 1170- 1172 ,(2011) , 10.1039/C0SC00538J
Katsuhiko Moriya, Kunihiko Tanaka, Hisao Uchiki, Characterization of Cu2ZnSnS4 Thin Films Prepared by Photo-Chemical Deposition Japanese Journal of Applied Physics. ,vol. 44, pp. 715- 717 ,(2005) , 10.1143/JJAP.44.715
Hironori Katagiri, Cu2ZnSnS4 thin film solar cells Thin Solid Films. ,vol. 480, pp. 426- 432 ,(2005) , 10.1016/J.TSF.2004.11.024