作者: Tarun Chandel , Vikas Thakur , Sona Halaszova , Michal Prochazka , Daniel Haško
DOI: 10.1007/S11664-018-6433-0
关键词: Nanocrystalline material 、 Secondary ion mass spectrometry 、 Thin film 、 Tetragonal crystal system 、 Band gap 、 Materials science 、 Kesterite 、 Analytical chemistry 、 CZTS 、 Scanning electron microscope
摘要: In the present study, we have synthesized single phase nanocrystalline Cu2ZnSnS4 (CZTS) thin films using spray pyrolysis technique. The were grown on glass substrates at 300°C and subsequently vacuum annealed for 1 h, different temperatures ranging from 350°C to 500°C. X-ray diffraction (XRD) studies show that crystallize in CZTS kesterite structure belonging tetragonal system. Atomic force microscopy scanning electron microscope together with XRD as-grown are made up of nano-sized (below 15 nm) particles CZTS. Secondary ion mass spectrometry shows uniform composition along depth except a surface layer which is slightly lower Cu content. Optical optical band gap values range reported film