Ablation plume particle dynamics during excimer laser ablation of polyimide

作者: D. W. Hahn , M. N. Ediger , G. H. Pettit

DOI: 10.1063/1.358745

关键词: Particle sizeAnalytical chemistryCarbonPlumeRaman spectroscopyExcimer laserScanning electron microscopeAblationMaterials scienceSoot

摘要: The dynamics of polyimide ablation plume particles generated during ArF excimer laser (193 nm) were investigated using time‐resolved, light scattering and Raman spectroscopy. evolution particle size is determined over a range 300–1150 μm above the polymer target surface. Raman‐scattering measurements allow in situ identification composition, which equivalent to flame soot. total mass particulate carbon within accounts for approximately 1% ablated polyimide. Scanning electron microscopy was used examine morphology collected particles, found correlate remarkably with light‐scattering results. formation apparently complete 500 surface, corresponding time scale 30 μs, then gives way oxidation at greater heights. It concluded tha...

参考文章(29)
J. H. Brannon, J. R. Lankard, A. I. Baise, F. Burns, J. Kaufman, Excimer laser etching of polyimide Journal of Applied Physics. ,vol. 58, pp. 2036- 2043 ,(1985) , 10.1063/1.336012
R. P. Rossman, W. R. Smith, Density of Carbon Black by Helium Displacement Industrial & Engineering Chemistry. ,vol. 35, pp. 972- 976 ,(1943) , 10.1021/IE50405A008
Donald L. Singleton, George Paraskevopoulos, Robert S. Irwin, XeCl laser ablation of polyimide: Influence of ambient atmosphere on particulate and gaseous products Journal of Applied Physics. ,vol. 66, pp. 3324- 3328 ,(1989) , 10.1063/1.344128
I.J. Jagoda, G. Prado, J. Lahaye, An experimental investigation into soot formation and distribution in polymer diffusion flames Combustion and Flame. ,vol. 37, pp. 261- 274 ,(1980) , 10.1016/0010-2180(80)90095-4
H.F. Calcote, Mechanisms of soot nucleation in flames—A critical review Combustion and Flame. ,vol. 42, pp. 215- 242 ,(1981) , 10.1016/0010-2180(81)90159-0
R. Srinivasan, Bodil Braren, Kelly G. Casey, Mildred Yeh, Ultrafast imaging of ultraviolet laser ablation and etching of polymethylmethacrylate Applied Physics Letters. ,vol. 55, pp. 2790- 2791 ,(1989) , 10.1063/1.101910
E. Sutcliffe, R. Srinivasan, Dynamics of UV laser ablation of organic polymer surfaces Journal of Applied Physics. ,vol. 60, pp. 3315- 3322 ,(1986) , 10.1063/1.337698
Peter L. G. Ventzek, Ronald M. Gilgenbach, Chi Hong Ching, Roger A. Lindley, Schlieren and dye laser resonance absorption photographic investigations of KrF excimer laser-ablated atoms and molecules from polyimide, polyethyleneterephthalate, and aluminum Journal of Applied Physics. ,vol. 72, pp. 1696- 1706 ,(1992) , 10.1063/1.351693