Determination of Emerging Substances in the Danube and Potential Risk Evaluation
作者： Nevena N. Grujić Letić , Maja Lj. Milanović , Nataša B. Milić , Mirjana B.Vojinović Miloradov , Jelena R. Radonić
关键词: Detection limit 、 Wastewater 、 Sulfamethoxazole 、 Caffeine 、 High-performance liquid chromatography 、 Sampling (statistics) 、 Repeatability 、 Chemistry 、 Environmental chemistry 、 Water quality
摘要: Seasonal variations of caffeine and antibiotic concentrations were investigated along the selected sites Danube using solid-phase extraction followed by high-performance liquid chromatography (HPLC). The potential risks on aquatic organisms evaluated. HPLC methods for determination modified validated showing good accuracy, repeatability, selectivity, robustness. obtained results confirmed presence at four sampling points, near wastewater discharges. mean summer, autumn, winter, spring 24.78, 26.83, 24.61, 86.29 ng/L, respectively. analyzed antibiotics (sulfamethoxazole, chloramphenicol, tiamuline) under limit detection in all tested samples taken from Danube. maximum risk indexes (MaxRIs) calculated each site. Four out seven showed sublethal effects with 10 < MaxRI < 100 (class II), while other three had no organisms. highest was site vicinity one biggest
sci-hub.se 参考文章(40)
Joaquín R. Domínguez-Vargas, Teresa Gonzalez, Patricia Palo, Eduardo M. Cuerda-Correa, Removal of Carbamazepine, Naproxen, and Trimethoprim from Water by Amberlite XAD‐7: A Kinetic Study Clean-soil Air Water. ,vol. 41, pp. 1052- 1061 ,(2013) , 10.1002/CLEN.201200245
R. Berg, M. Schwieder, J. A. Marshman, R. M. Gilbert, Caffeine content of beverages as consumed Canadian Medical Association Journal. ,vol. 114, pp. 205- 208 ,(1976)
Robert Loos, Jan Wollgast, Tania Huber, Georg Hanke, Polar herbicides, pharmaceutical products, perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), and nonylphenol and its carboxylates and ethoxylates in surface and tap waters around Lake Maggiore in Northern Italy Analytical and Bioanalytical Chemistry. ,vol. 387, pp. 1469- 1478 ,(2007) , 10.1007/S00216-006-1036-7
Robert Loos, Giovanni Locoro, Serafino Contini, Occurrence of polar organic contaminants in the dissolved water phase of the Danube River and its major tributaries using SPE-LC-MS2 analysis Water Research. ,vol. 44, pp. 2325- 2335 ,(2010) , 10.1016/J.WATRES.2009.12.035
Tina R. Norton, Amy B. Lazev, MacKenzie J. Sullivan, The “Buzz” on Caffeine: Patterns of Caffeine Use in a Convenience Sample of College Students Journal of caffeine research. ,vol. 1, pp. 35- 40 ,(2011) , 10.1089/JCR.2010.0003
Klaus Kümmerer, Emerging Contaminants versus Micro-pollutants Clean-soil Air Water. ,vol. 39, pp. 889- 890 ,(2011) , 10.1002/CLEN.201110002
Zoe Rodriguez del Rey, Elise F. Granek, Steve Sylvester, Occurrence and concentration of caffeine in Oregon coastal waters. Marine Pollution Bulletin. ,vol. 64, pp. 1417- 1424 ,(2012) , 10.1016/J.MARPOLBUL.2012.04.015
Kyungho Choi, Younghee Kim, Jeongim Park, Chan Koo Park, MinYoung Kim, Hyun Soo Kim, Pangyi Kim, Seasonal variations of several pharmaceutical residues in surface water and sewage treatment plants of Han River, Korea. Science of The Total Environment. ,vol. 405, pp. 120- 128 ,(2008) , 10.1016/J.SCITOTENV.2008.06.038
Ignaz J. Buerge, Thomas Poiger, Markus D. Müller, Hans-Rudolf Buser, Caffeine, an Anthropogenic Marker for Wastewater Contamination of Surface Waters Environmental Science & Technology. ,vol. 37, pp. 691- 700 ,(2003) , 10.1021/ES020125Z
Sandra Babić, Danijela Ašperger, Dragana Mutavdžić, Alka J.M. Horvat, Marija Kaštelan-Macan, Solid phase extraction and HPLC determination of veterinary pharmaceuticals in wastewater Talanta. ,vol. 70, pp. 732- 738 ,(2006) , 10.1016/J.TALANTA.2006.07.003