New NADH models bearing a phosphonate or a chiral oxazaphospholidine oxide at the dihydropyridine ring
作者： Jean-Luc Vasse , Sophie Goumain , Vincent Levacher , Georges Dupas , Guy Quéguiner
DOI: 10.1016/S0040-4039(01)00027-2
关键词: Oxide 、 Chemistry 、 Ketone 、 Combinatorial chemistry 、 Stereochemistry 、 Ring (chemistry) 、 Bearing (mechanical) 、 Phosphonate 、 Dihydropyridine
摘要: Abstract Novel NADH models bearing a phosphonate at the 3-position of stable 1,4-dihydroquinoline structure were successfully involved in reduction methyl benzoylformate. Asymmetric former ketone with model chiral oxazaphospholidine oxide is reported affording benzoylformate 45% e.e.
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