An unexpected product arising from metal alkylidene mediated ring-closing diene metathesis

作者: Daisy Joe , Larry E. Overman

DOI: 10.1016/S0040-4039(97)10373-2

关键词: DieneChemistryMetathesisAcyclic diene metathesisRing-opening metathesis polymerisationMedicinal chemistryRing (chemistry)StereochemistryMetal

摘要: Abstract Ring-closing diene metathesis of siloxytriene 3 surprisingly afforded siloxytricycle 9 in which the newly formed ring is one carbon unit smaller than expected.

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