Molybdenum-oxo chemistry in various aspects of oxygen atom transfer processes
作者： H. Arzoumanian
DOI: 10.1016/S0010-8545(98)00056-3
关键词: Tautomer 、 Molybdenum 、 Organic chemistry 、 Chemistry 、 Electron 、 Computational chemistry 、 Proximity effect (atomic physics) 、 Transfer agent 、 Oxygen atom
摘要: Abstract In the very important field of transition-metal chemistry, this paper describes three characteristics molybdenum-oxo entity, underlying its versatility: first role it can play as an electron well, exemplified by a “proximity effect”, second basic character MoO function, shown in “pseudo keto-enol” tautomeric transformation, and finally oxygen atom transfer agent, illustrated thiocyanatodioxo molybdenum(VI) complex.
elsevier.com
sci-hub.se 参考文章(37)
Frank Bottomley, Lori Sutin, Organometallic Compounds Containing Oxygen Atoms Advances in Organometallic Chemistry. ,vol. 28, pp. 339- 396 ,(1988) , 10.1016/S0065-3055(08)60117-3
Jay K. Kochi, Roger A. Sheldon, Metal-catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic Methodology Including Biochemical Processes ,(1981)
E.J. Corey, J.William Suggs, PYRIDINIUM CHLOROCHROMATE, AN EFFICIENT REAGENT FOR OXIDATION OF PRIMARY AND SECONDARY ALCOHOLS TO CARBONYL COMPOUNDS Tetrahedron Letters. ,vol. 16, pp. 2647- 2650 ,(1975) , 10.1016/S0040-4039(00)75204-X
G. N. Schrauzer, E. O. Schlemper, Liu Nan. Hui, K. Rubin, Ximu. Zhang, Xiping. Long, Chong Shik. Chin, Studies of molybdenum compounds. 5. Diethyl(2,2'-bipyridyl)dioxomolybdenum(VI) and other higher dialkyl derivatives of dioxomolybdenum(VI) Organometallics. ,vol. 5, pp. 2452- 2456 ,(1986) , 10.1021/OM00143A008
Anthony K. Rappe, William A. Goddard, Olefin metathesis - a mechanistic study of high-valent Group VI catalysts Journal of the American Chemical Society. ,vol. 104, pp. 448- 456 ,(1982) , 10.1021/JA00366A013
Cheng Zhang, Elmer O. Schlemper, Gerhard N. Schrauzer, Synthesis, structure, and reactions of 2,2'-bipyridyl complexes of tetramethyloxotungsten(VI) and dimethyldioxotungsten(VI) and of related compounds Organometallics. ,vol. 9, pp. 1016- 1020 ,(1990) , 10.1021/OM00118A018
Ambrogio. Giacomelli, Carlo. Floriani, Adalcindo Ofir De Souza. Duarte, Angiola. Chiesi-Villa, Carlo. Guastini, Chemistry and structure of an inorganic analog of a carboxylic acid: hydroxobis(8-quinolinato)oxovanadium(V) Inorganic Chemistry. ,vol. 21, pp. 3310- 3316 ,(1982) , 10.1021/IC00139A012
Laura K. Stultz, Robert A. Binstead, Martha S. Reynolds, Thomas J. Meyer, Epoxidation of olefins by [RuIV(bpy)2(py)(O)]2+ in acetonitrile solution. A global kinetic analysis of the epoxidation of trans-stilbene Journal of the American Chemical Society. ,vol. 117, pp. 2520- 2532 ,(1995) , 10.1021/JA00114A015
Henri Arzoumanian, Giuseppe Agrifoglio, Heinz Krentzien, Mario Capparelli, Arylalkane oxidation by dioxo[4,4′-di(tert-butyl)-2,2′-bipyridyl]molybdenum(VI) complexes Journal of The Chemical Society, Chemical Communications. pp. 655- 656 ,(1995) , 10.1039/C39950000655
Robert A. Moss, Masatoshi Matsuo, “Extended deaminations” -- reactions of alkane diazotates with thionyl chloride Tetrahedron Letters. ,vol. 17, pp. 1963- 1966 ,(1976) , 10.1016/S0040-4039(00)78090-7