Silicon‐Assisted Direct Covalent Grafting on Metal Oxide Surfaces: Synthesis and Characterization of Carboxylate N,N′‐Ligands on TiO2
作者： Henri Arzoumanian , Nelson J. Castellanos , Fernando O. Martínez , Edgar A. Páez-Mozo , Fabio Ziarelli
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摘要: The easy covalent bonding of an OH-bearing molecule onto a metal oxide surface can be done by transesterifying trimethylsilylated hydroxy function with the OH groups. This results in grafting organic directly on matrix, accompanied formation trimethylsilanol, which easily eliminated as volatile hexamethyldisiloxane and water. was accomplished TiO 2 matrix three carboxylic acids: acetic, isonicotinic, 2,2'-bipyridyl-4,4'-dicarboxylic acids. N,N'-immobilized ligand then used for dioxidomolybdenum entity tested such at room temperature under atmospheric pressure O oxidation ethylbenzene. All intermediates grafted species were fully characterized 13 CMAS NMR spectroscopy, thermogravimetric elemental analysis.
sci-hub.se 参考文章(50)
Fabrice Gritti, Georges Guiochon, Influence of the pressure on the properties of chromatographic columns. I. Measurement of the compressibility of methanol-water mixtures on a mesoporous silica adsorbent Journal of Chromatography A. ,vol. 1070, pp. 1- 12 ,(2005) , 10.1016/J.CHROMA.2005.02.007
Tewodros Asefa, Mark J. MacLachlan, Neil Coombs, Geoffrey A. Ozin, Periodic mesoporous organosilicas with organic groups inside the channel walls Nature. ,vol. 402, pp. 867- 871 ,(1999) , 10.1038/47229
André Sarto Polo, Melina Kayoko Itokazu, Neyde Yukie Murakami Iha, Metal complex sensitizers in dye-sensitized solar cells Coordination Chemistry Reviews. ,vol. 248, pp. 1343- 1361 ,(2004) , 10.1016/J.CCR.2004.04.013
Md.K. Nazeeruddin, C. Klein, P. Liska, M. Grätzel, Synthesis of novel ruthenium sensitizers and their application in dye-sensitized solar cells Coordination Chemistry Reviews. ,vol. 249, pp. 1460- 1467 ,(2005) , 10.1016/J.CCR.2005.03.025
Jean Desilvestro, Michael Graetzel, Ladislav Kavan, Jacques Moser, Jan Augustynski, Highly efficient sensitization of titanium dioxide Journal of the American Chemical Society. ,vol. 107, pp. 2988- 2990 ,(1985) , 10.1021/JA00296A035
A. S. Foster, R. M. Nieminen, Adsorption of acetic and trifluoroacetic acid on the TiO2(110) surface The Journal of Chemical Physics. ,vol. 121, pp. 9039- 9042 ,(2004) , 10.1063/1.1802652
O.B. Peersen, X.L. Wu, I. Kustanovich, S.O. Smith, Variable-Amplitude Cross-Polarization MAS NMR Journal of Magnetic Resonance, Series A. ,vol. 104, pp. 334- 339 ,(1993) , 10.1006/JMRA.1993.1231
Karin Moller, Thomas Bein, Inclusion Chemistry in Periodic Mesoporous Hosts Chemistry of Materials. ,vol. 10, pp. 2950- 2963 ,(1998) , 10.1021/CM980243E
Reza Dabestani, Allen J. Bard, Alan Campion, Marye Anne Fox, Thomas E. Mallouk, Stephen E. Webber, J. M. White, Sensitization of titanium dioxide and strontium titanate electrodes by ruthenium(II) tris(2,2'-bipyridine-4,4'-dicarboxylic acid) and zinc tetrakis(4-carboxyphenyl)porphyrin: an evaluation of sensitization efficiency for component photoelectrodes in a multipanel device The Journal of Physical Chemistry. ,vol. 92, pp. 1872- 1878 ,(1988) , 10.1021/J100318A035
Gerald L. Larson, Antonio Hernandez, Reaction of trimethylsilyl enol ethers with diols Journal of Organic Chemistry. ,vol. 38, pp. 3935- 3936 ,(1973) , 10.1021/JO00962A025