Heterolytic dihydrogen activation by B(C6F5)3 and carbonyl compounds
作者： Markus Lindqvist , Nina Sarnela , Victor Sumerin , Konstantin Chernichenko , Markku Leskelä
DOI: 10.1039/C2DT12268E
关键词: Borane 、 Heterolysis 、 Carbene 、 Metal 、 Medicinal chemistry 、 Photochemistry 、 Main group element 、 Chemistry 、 Reactivity (chemistry) 、 Adduct 、 Frustrated Lewis pair
摘要: Aromatic carbonyl compounds in combination with B(C6F5)3 are able to activate H2 heterolytically. The reactivity of the carbonyl–B(C6F5)3 adduct is initiated by its thermal dissociation into components. After addition, aromatic convert aryl-substituted methanes or alcohols.
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