Consolidation of the Cu46Zr42Al7Y5 amorphous ribbons and powder alloy by hot extrusion

作者: Ana Karla Melle , Mauricio Mhirdaui Peres , Claudemiro Bolfarini , Walter José Botta , Alberto Moreira Jorge Junior

DOI: 10.1590/S1516-14392012005000095

关键词: Consolidation (soil)MetallurgyScanning electron microscopeAmorphous metalAlloyDifferential scanning calorimetrySupercoolingAmorphous solidExtrusionMaterials science

摘要: The amorphous Cu46Zr42Al7Y5 alloy presents large supercooled liquid region (ΔTX = 100 K), with a viscosity of about 106 N.s/m2 where the material can flow as liquid, making it possible an easy deformation in this temperature region. aim work was to analyze processing routes produce bulks metallic glasses. Two kinds materials were used: powders and ribbons, both consolidated by hot extrusion temperatures inside range between Tg Tx, ram speed 1 mm/min ratio 3 : 1. Analysis X-Ray Diffratometry (XRD), Differential Scanning Calorimetry (DSC) Electron Microscopy (SEM), revealed that proposed consolidation effective materials, even strong decreasing ΔTX observed after milling during extrusion.

参考文章(13)
Hidemi Kato, Yoshihito Kawamura, Akihisa Inoue, Tsuyoshi Masumoto, Bulk glassy Zr-based alloys prepared by consolidation of glassy alloy powders in supercooled liquid region Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. pp. 458- 462 ,(1997) , 10.1016/S0921-5093(96)10664-X
Tang Mei-Bo, Zhao De-Qian, Pan Ming-Xiang, Wang Wei-Hua, Binary Cu–Zr Bulk Metallic Glasses Chinese Physics Letters. ,vol. 21, pp. 901- 903 ,(2004) , 10.1088/0256-307X/21/5/039
T.G Nieh, T Mukai, C.T Liu, J Wadsworth, Superplastic behavior of a Zr-10Al-5Ti-17.9Cu-14.6Ni metallic glass in the supercooled liquid region Scripta Materialia. ,vol. 40, pp. 1021- 1027 ,(1999) , 10.1016/S1359-6462(99)00071-8
Akihisa Inoue, Wei Zhang, Formation, Thermal Stability and Mechanical Properties of Cu-Zr-Al Bulk Glassy Alloys Materials Transactions. ,vol. 43, pp. 2921- 2925 ,(2002) , 10.2320/MATERTRANS.43.2921
An-hui Cai, Xiang Xiong, Yong Liu, Yong Zhou, Wei-ke An, Yun Luo, Regular Cu-based amorphous alloy powder Journal of Alloys and Compounds. ,vol. 497, pp. 234- 238 ,(2010) , 10.1016/J.JALLCOM.2010.03.018
H FU, H WANG, H ZHANG, Z HU, The effect of Gd addition on the glass-forming ability of Cu-Zr-Al alloy Scripta Materialia. ,vol. 55, pp. 147- 150 ,(2006) , 10.1016/J.SCRIPTAMAT.2006.03.052
J.K. Lee, H.J. Kim, T.S. Kim, Y.C. Kim, J.C. Bae, Consolidation behavior of Cu- and Ni-based bulk metallic glass composites Journal of Alloys and Compounds. ,vol. 434, pp. 336- 339 ,(2007) , 10.1016/J.JALLCOM.2006.08.304
M.K. Tam, S.J. Pang, C.H. Shek, Effects of niobium on thermal stability and corrosion behavior of glassy Cu–Zr–Al–Nb alloys Journal of Physics and Chemistry of Solids. ,vol. 67, pp. 762- 766 ,(2006) , 10.1016/J.JPCS.2005.11.012
Donghua Xu, Gang Duan, William L. Johnson, Unusual Glass-Forming Ability of Bulk Amorphous Alloys Based on Ordinary Metal Copper Physical Review Letters. ,vol. 92, pp. 245504- ,(2004) , 10.1103/PHYSREVLETT.92.245504
Donghua Xu, Boonrat Lohwongwatana, Gang Duan, William L. Johnson, Carol Garland, Bulk metallic glass formation in binary Cu-rich alloy series – Cu100−xZrx (x=34, 36, 38.2, 40 at.%) and mechanical properties of bulk Cu64Zr36 glass Acta Materialia. ,vol. 52, pp. 2621- 2624 ,(2004) , 10.1016/J.ACTAMAT.2004.02.009