Nitrogen-14 and chlorine-35-quadrupole resonance in some N-(1-chloro-2,4-diazabut-3-enylidene)-N,N-dimethylammonium salts

作者: Gerhard V. Boyd , Mian M. P. Khurshid , George A. Nicolaou , John A. S. Smith

DOI: 10.1039/P29880000933

关键词: ResonanceStereochemistryChemistryIsotopes of chlorineCrystallographyImineEtherNitrogenQuadrupoleZeeman effectCross relaxation

摘要: Nitrogen-14 and chlorine-35 quadrupole resonance frequencies have been measured at room temperature for a series of six closely related N·(1-chloro-2,4-diazabut-3-enylidene)-N,N-dimethylammonium salts two compounds. Reasonable assignments all 14N made their variations with structure are discussed. The results support the R1NCR2-NH–CClNMe2X– examined; it appears to be predominant from, cation has therefore named on this basis.

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