Visible-light-triggered direct keto-difluoroacetylation of styrenes with (fluorosulfonyl)difluoroacetate and dimethyl sulfoxide leads to α-difluoroacetylated ketones.
作者： Xuewei Luo , Zhengning Fan , Bo Zhang , Chao Chen , Chanjuan Xi
DOI: 10.1039/C9CC06037E
关键词: Photochemistry 、 Visible spectrum 、 Dimethyl sulfoxide 、 Chemistry 、 Visible light irradiation 、 Photocatalysis
摘要: Photoredox-catalyzed direct keto-difluoroacetylation of styrenes with (fluorosulfonyl)difluoroacetate and dimethyl sulfoxide as an oxidant is disclosed. A variety α-difluoroacetylated ketones bearing functional groups good yields are obtained using fac-Ir(ppy)3 a photocatalyst under visible light irradiation.
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