Cycloaddition of acetylenedicarbaldehyde monoacetal and 2,4,5-trithioxo-1,3-dithiole: Ready access to novel highly extended and sulfur-rich analogues of tetrathiafulvalene (TTF)
作者： Philippe Leriche , Alain Gorgues , Michel Jubault , Jan Becher , Jesús Orduna
DOI: 10.1016/0040-4039(95)00014-4
关键词: Tetrathiafulvalene 、 Chemistry 、 Organic chemistry 、 Combinatorial chemistry 、 Reagent 、 Sulfur 、 Cycloaddition
摘要: Abstract Thiones 2 (′), 4 (′) and 3 are readily prepared from title compounds. Bis-olefinations of with Akiba's reagents W or H afford 8 which can cyclize into 9 upon acid areatment. ( i -PrO) P mediated coupling 5′ affords 7 whose formolysis in 10 bis-olefination yields target compound 1 . The π-donor ability stability discussed.
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