Synthesis and redox properties of largely π-extended p-quinodimethane analogues of tetrathiafulvalene
作者： Nazario Martín , Luis Sánchez , Carlos Seoane , Carolina Fernández , None
DOI: 10.1016/0379-6779(96)80114-7
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摘要: Abstract The highest known π -extended tetrathiafulvalene (TTF) analogues with a quinoid structure are reported; the cyclic voltammetry data reveal their strong donor character involving two-electron oxidation wave to dication when two dithiole rings present in molecule. A molecule bearing only unit has been prepared from benz[ g ]anthrone by Wittig-Horner reaction and its electrochemical presence of one-electron waves form radical cation dication; charge transfer complexes formed electron acceptors showing mixed valence character.
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