Electrocatalytic reduction of nitrite ion by edta complexes of iron(II) and ruthenium(II)

作者: Matthew R. Rhodes , Mark H. Barley , Thomas J. Meyer

DOI: 10.1021/IC00004A008

关键词: ChemistryElectrochemistryNitriteElectrocatalystRutheniumPotassium phosphateReaction mechanismMERCURENitrite ionInorganic chemistry

摘要: The reductive electrochemistries of both [Ru II (Hedta)(NO + )] 0 and [Fe • − have been investigated as a function pH. nitrosyl complexes are effective electrocatalysts for the reduction NO 2 or HONO to give reduced products N O, , NH 3 OH 4

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