Preparation and magnetization of hematite nanocrystals with amorphous iron oxide layers by hydrothermal conditions

作者: G.S. Li , R.L. Smith , H. Inomata , K. Arai

DOI: 10.1016/S0025-5408(02)00695-5

关键词: Iron oxideInorganic chemistryHydrothermal circulationHydrothermal synthesisCrystallizationCoercivityAmorphous solidNanocrystalMaterials scienceHematite

摘要: Abstract Hematite nanocrystals modified with surface layers of amorphous hydrous iron oxides were prepared by hydrothermal conditions in the absence alkali. The formation temperature was found to be ca. 130°C. When lower than 130°C, no product formed, while above this temperature, amount at hematite drastically decreased. on obtained 130°C determined Fe2O3·1.64H2O. coercivity for 0.534 kOe, which is slightly larger values few agglomerations.

参考文章(14)
M. Schultz, W. Burckhardt, St. Barth, Investigations on thermally forced hydrolysis and phase formation in aqueous iron(III) nitrate solutions Journal of Materials Science. ,vol. 34, pp. 2217- 2227 ,(1999) , 10.1023/A:1004553019739
Egon Matijević, Paul Scheiner, Ferric hydrous oxide sols Journal of Colloid and Interface Science. ,vol. 63, pp. 509- 524 ,(1978) , 10.1016/S0021-9797(78)80011-3
C. Rath, K. K. Sahu, S. D. Kulkarni, S. Anand, S. K. Date, R. P. Das, N. C. Mishra, Microstructure-dependent coercivity in monodispersed hematite particles Applied Physics Letters. ,vol. 75, pp. 4171- 4173 ,(1999) , 10.1063/1.125572
H. Sesigur, E. Acma, O. Addemir, A. Tekin, The preparation of magnetic iron oxide Materials Research Bulletin. ,vol. 31, pp. 1573- 1579 ,(1996) , 10.1016/S0025-5408(96)00155-9
Masanori Hirano, Yuji Fukuda, Hiroyuki Iwata, Yuji Hotta, Michio Inagaki, Preparation and Spherical Agglomeration of Crystalline Cerium(IV) Oxide Nanoparticles by Thermal Hydrolysis Journal of the American Ceramic Society. ,vol. 83, pp. 1287- 1289 ,(2004) , 10.1111/J.1151-2916.2000.TB01371.X
Richard A Eggleton, Robert W Fitzpatrick, New Data and a Revised Structural Model for Ferrihydrite Clays and Clay Minerals. ,vol. 36, pp. 111- 124 ,(1988) , 10.1346/CCMN.1988.0360203
M. Ocaña, M.P. Morales, C.J. Serna, Homogeneous Precipitation of Uniform α-Fe2O3Particles from Iron Salts Solutions in the Presence of Urea Journal of Colloid and Interface Science. ,vol. 212, pp. 317- 323 ,(1999) , 10.1006/JCIS.1998.6042
Lucian Diamandescu, Doina Mihaila-Tarabasanu, Nicoleta Popescu-Pogrion, Alina Totovina, Ion Bibicu, Hydrothermal synthesis and characterization of some polycrystalline α-iron oxides Ceramics International. ,vol. 25, pp. 689- 692 ,(1999) , 10.1016/S0272-8842(99)00002-4
Liping Li, Guangshe Li, R. L. Smith,, H. Inomata, Microstructural Evolution and Magnetic Properties of NiFe2O4 Nanocrystals Dispersed in Amorphous Silica Chemistry of Materials. ,vol. 12, pp. 3705- 3714 ,(2000) , 10.1021/CM000481L
L. Suber, D. Fiorani, P. Imperatori, S. Foglia, A. Montone, R. Zysler, Effects of thermal treatments on structural and magnetic properties of acicular α-Fe2O3 nanoparticles Nanostructured Materials. ,vol. 11, pp. 797- 803 ,(1999) , 10.1016/S0965-9773(99)00369-4