Design Aspects for the Development of Mixed-Metal Supramolecular Complexes Capable of Visible Light Induced Photocleavage of DNA

作者: Alvin A. Holder , Shawn Swavey , Karen J. Brewer

DOI: 10.1021/IC035029T

关键词: ChemistrySupramolecular chemistryLigandRhodiumPhotochemistryOsmiumPyrazineExcited stateRutheniumMetal

摘要: … In such complexes, 1 MLCT excitation is then followed by conversion to a reactive 3 MMCT … without a low lying MMCT state allow us to establish the role of this MMCT state in the DNA …

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