Poly(methyl acrylate)/poly(hydroxyethyl acrylate) sequential interpenetrating polymer networks. Miscibility and water sorption behavior
作者： J. L. G�mez Ribelles , M. Monle�n Pradas , G. Gallego Ferrer , N. Peidro Torres , V. P�rez Gim�nez
DOI: 10.1002/(SICI)1099-0488(19990715)37:14<1587::AID-POLB4>3.0.CO;2-U
关键词: Radical polymerization 、 Materials science 、 Poly(methyl acrylate) 、 Methyl acrylate 、 Polymer chemistry 、 Polymerization 、 Miscibility 、 Interpenetrating polymer network 、 Glass transition 、 Acrylate
摘要: Sequential poly(methyl acrylate)/poly(hydroxyethyl acrylate) interpenetrating polymer networks with different poly(hydroxyethyl contents were prepared by free radical polymerization of hydroxyethyl acrylate inside the previously polymerized network. Differential scanning calorimetry on dry samples shows that exhibit phase separation, and no differences are found between glass transition temperatures two phases present in network those pure components. Thermally stimulated depolarization current experiments used to study influence water sorption mobility molecular groups Isothermal is analyzed theories compare behavior Diffusion coefficients obtained means dynamic experiments. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Phys 37: 1587–1599,
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