R-matrix calculation of the bound and continuum states of the - system
作者： I Rabadán , J Tennyson
DOI: 10.1088/0953-4075/29/16/018
关键词: Continuum (design consultancy) 、 Rydberg atom 、 Quantum defect 、 Physics 、 Rydberg constant 、 Wave function 、 Rydberg formula 、 Atomic physics 、 Excited state 、 Hydrogen spectral series 、 Quantum mechanics
摘要: A comprehensive theoretical study of NO Rydberg states and Feshbach resonances associated with excited is made for an internuclear separation 2.175 . Calculations are performed using the UK R-matrix molecular package. The lowest four target (, , ) considered in construction CI wavefunction. Quantum defect theory employed to analyse multiple series obtained. In bound-states region spectrum, six resolved quantum defects given up n = 11. continuum converging three identified compared available experimental data. Some previous assignments both bound reinterpreted dominant source partial-wave mixing re-analysed. Data resonance widths presented first time.
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sci-hub.se 参考文章(28)
Susanne Fredin, Dolores Gauyacq, Marcel Horani, Christian Jungen, Georges Lefevre, Françoise Masnou-Seeuws, s and d Rydberg series of NO probed by double resonance multiphoton ionization Molecular Physics. ,vol. 60, pp. 825- 866 ,(1987) , 10.1080/00268978700100571
Robert Jastrow, On the Rydberg-Ritz Formula in Quantum Mechanics Physical Review. ,vol. 73, pp. 60- 67 ,(1948) , 10.1103/PHYSREV.73.60
M Fehér, PA Martin, None, Ab initio calculations of the properties of NO + in its ground electronic state X 1 Σ + Chemical Physics Letters. ,vol. 215, pp. 565- 570 ,(1993) , 10.1016/0009-2614(93)89356-M
J. Guo, A. Mank, J. W. Hepburn, Photoelectron angular distributions of rotationally selected NO Rydberg states. Physical Review Letters. ,vol. 74, pp. 3584- 3587 ,(1995) , 10.1103/PHYSREVLETT.74.3584
Forrest R. Gilmore, Potential energy curves for N2, NO, O2 and corresponding ions Journal of Quantitative Spectroscopy and Radiative Transfer. ,vol. 5, pp. 369- IN3 ,(1965) , 10.1016/0022-4073(65)90072-5
Frank P. Billingsley, Multiconfiguration self‐consistent‐field calculation of the dipole moment function and potential curve of NO(X2Π) Journal of Chemical Physics. ,vol. 62, pp. 864- 874 ,(1975) , 10.1063/1.430537
Lei Liu, Jia-Ming Li, The electronic structure of molecular Rydberg states of diatomic molecules Journal of Physics B. ,vol. 24, pp. 1893- 1898 ,(1991) , 10.1088/0953-4075/24/8/007
Asuka Fujii, Takayuki Ebata, Mitsuo Ito, Vacuum ultraviolet-visible double resonance spectroscopy of NO. Observation of the high excited ns and nd Rydberg series Journal of Chemical Physics. ,vol. 90, pp. 6993- 6999 ,(1989) , 10.1063/1.456274
Jonathan Tennyson, Cliff J. Noble, RESON—A program for the detection and fitting of Breit-Wigner resonances Computer Physics Communications. ,vol. 33, pp. 421- 424 ,(1984) , 10.1016/0010-4655(84)90147-4
Richard J. Stubbs, Trevor A. York, John Comer, Electron energy-loss studies of nitric oxide Chemical Physics. ,vol. 106, pp. 161- 170 ,(1986) , 10.1016/0301-0104(86)87047-1