Metal Ions Doped Complex Cobalt Blue Pigment Research
作者： Ming Quan Ye , Ai Jun Han , Zhu Bo Liu , Chen Wang
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.415-417.194
关键词: Doping 、 Spinel 、 Crystal structure 、 Ionic radius 、 Crystallography 、 Materials science 、 Cobalt blue 、 Lattice constant 、 Metal ions in aqueous solution 、 Inorganic chemistry 、 Solid solution
摘要: Metal ions doped complex cobalt blue pigments are prepared by homogeneous precipitation, to investigate the effects of doping Zn2+ ，Mg2+ ，Ni2+ and Y 3+ on some properties pigments, such as crystal structure, color, shading power temperature resistance. Studies have shown that little effect spinel type resistance ; ionic radius differences between Co2 + cause lattice distortion changes constant , thus affecting ligand state spaces ion, color pigment. The Zn2 becomes larger with increasing amount while Mg2 +and Ni2 constants become smaller; when Y3 enter into CoAl2O4 lattice, replacing hexa-coordinate octahedral gap Al3 Al3+cause distortion, 3 increases a certain extent, phase in form Y2O3 will be generated it maybe kind CoYxAl2-xO4- solid solution instead complete structure.
sci-hub.se 参考文章(22)
Marcos Zayat, David Levy, Surface Area Study of High Area Cobalt Aluminate Particles Prepared by the Sol-Gel Method Journal of Sol-Gel Science and Technology. ,vol. 25, pp. 201- 206 ,(2002) , 10.1023/A:1020287307107
Richard E Riman, Wojciech L Suchanek, Malgorzata M Lencka, None, Hydrothermal crystallization of ceramics Annales De Chimie-science Des Materiaux. ,vol. 27, pp. 15- 36 ,(2002) , 10.1016/S0151-9107(02)90012-7
G. Carta, M. Casarin, N. El Habra, M. Natali, G. Rossetto, C. Sada, E. Tondello, P. Zanella, MOCVD deposition of CoAl2O4 films Electrochimica Acta. ,vol. 50, pp. 4592- 4599 ,(2005) , 10.1016/J.ELECTACTA.2004.10.094
G HU, X DENG, Y CAO, Z PENG, Synthesis of spherical CoAl2O4 pigment particles with high reflectivity by polymeric-aerosol pyrolysis Rare Metals. ,vol. 26, pp. 236- 241 ,(2007) , 10.1016/S1001-0521(07)60208-3
Weidong Li, Jiazhi Li, Jingkun Guo, Synthesis and characterization of nanocrystalline CoAl2O4 spinel powder by low temperature combustion Journal of The European Ceramic Society. ,vol. 23, pp. 2289- 2295 ,(2003) , 10.1016/S0955-2219(03)00081-5
J CUNHA, D MELO, A MARTINELLI, M MELO, I MAIA, S CUNHA, Ceramic pigment obtained by polymeric precursors Dyes and Pigments. ,vol. 65, pp. 11- 14 ,(2005) , 10.1016/J.DYEPIG.2004.06.005
D.M.A. Melo, J.D. Cunha, J.D.G. Fernandes, M.I. Bernardi, M.A.F. Melo, A.E. Martinelli, Evaluation of CoAl2O4 as ceramic pigments Materials Research Bulletin. ,vol. 38, pp. 1559- 1564 ,(2003) , 10.1016/S0025-5408(03)00136-3
Markus Lade, Holger Mays, Jörg Schmidt, Regine Willumeit, Reinhard Schomäcker, On the nanoparticle synthesis in microemulsions: detailed characterization of an applied reaction mixture Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 163, pp. 3- 15 ,(2000) , 10.1016/S0927-7757(99)00425-2
M. Llusar, A. Forés, J.A. Badenes, J. Calbo, M.A. Tena, Guillermo Monrós, Colour analysis of some cobalt-based blue pigments Journal of The European Ceramic Society. ,vol. 21, pp. 1121- 1130 ,(2001) , 10.1016/S0955-2219(00)00295-8
D. Jonynaite, J. Senvaitiene, A. Beganskiene, A. Kareiva, Spectroscopic analysis of blue cobalt smalt pigment Vibrational Spectroscopy. ,vol. 52, pp. 158- 162 ,(2010) , 10.1016/J.VIBSPEC.2009.12.005