Amorphization, Crystallization, and Magnetic Properties of Melt-Spun Alloys

作者: Liya Li , Wei Xie

DOI: 10.1155/2011/910268

关键词: RemanenceAnnealing (metallurgy)CoercivityRibbonGrain sizeAnalytical chemistryCrystallizationMelt spinningAmorphous solidMaterials scienceCrystallography

摘要: Effects of Cr3C2 content and wheel surface speed on the amorphous formation ability magnetic properties have been investigated for melt-spun () alloys. Ribbon at lower (30 m/s) has composite structure composed mostly SmCo7, a small amount Sm2Co17, residual phases. The grain size SmCo7 phase decreases with increase . When melt spinning 40 m/s, alloys can be obtained in state intrinsic coercive order 40–70 Oe. DSC analysis reveals that first precipitates from matrix 650∘C, followed by crystallization Sm2Co17 770∘C. Optimal coercivity 7.98 kOe remanent magnetization 55.05 emu/g realized magnet subjected to 40 m/s annealing 650∘C 5 min. domain annealed ribbon is interaction domains typically 100–400 nm size, which indicates presence strong exchange coupling between grains.

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