Mediating Order and Modulating Porosity by Controlled Hydrolysis in a Phosphonate Monoester Metal–Organic Framework
作者： Benjamin S. Gelfand , Racheal P. S. Huynh , Roger K. Mah , George K. H. Shimizu
关键词: Porosity 、 Metal-organic framework 、 Phosphonate 、 Inorganic chemistry 、 Hydrolysis 、 Sorption 、 Copper 、 Selectivity 、 Adsorption 、 Chemistry
摘要: A crystalline and permanently porous copper phosphonate monoester framework has been synthesized from a tetraaryl trigonal linker. This material surface area over 1000 m2 g−1, as measured by N2 sorption, the highest reported for phosphonate-based metal–organic (MOF). The monoesters result in hydrophobic pore surfaces that give low heat of adsorption CO2 calculated selectivity CH4 binary mixtures. By careful manipulation synthetic conditions, it is possible to selectively remove some lining form hydrogen while giving an isomorphous structure. increases affinity higher ambient uptake, adsorption, much both CH4. Formation acid groups noteworthy complexation with parent gives different
sci-hub.se 参考文章(42)
Atsushi Kondo, Tokuya Satomi, Kanami Azuma, Rie Takeda, Kazuyuki Maeda, New layered copper 1,3,5-benzenetriphosphonates pillared with N-donor ligands: their synthesis, crystal structures, and adsorption properties Dalton Transactions. ,vol. 44, pp. 12717- 12725 ,(2015) , 10.1039/C5DT01137J
Kazuyuki Maeda, Yoshimichi Kiyozumi, Fujio Mizukami, Synthese des ersten mikroporösen Aluminiumphosphonats mit kovalent an das Gerüst gebundenen organischen Gruppen Angewandte Chemie. ,vol. 106, pp. 2427- 2428 ,(1994) , 10.1002/ANGE.19941062234
Jason M. Simmons, Hui Wu, Wei Zhou, Taner Yildirim, Carbon capture in metal–organic frameworks—a comparative study Energy and Environmental Science. ,vol. 4, pp. 2177- 2185 ,(2011) , 10.1039/C0EE00700E
Tania Rodenas, Ignacio Luz, Gonzalo Prieto, Beatriz Seoane, Hozanna Miro, Avelino Corma, Freek Kapteijn, Francesc X. Llabrés i Xamena, Jorge Gascon, Metal–organic framework nanosheets in polymer composite materials for gas separation Nature Materials. ,vol. 14, pp. 48- 55 ,(2015) , 10.1038/NMAT4113
Michael T. Wharmby, Gordon M. Pearce, John P.S. Mowat, John M. Griffin, Sharon E. Ashbrook, Paul A. Wright, Lars-Hendrik Schilling, Alexandra Lieb, Norbert Stock, Sachin Chavan, Silvia Bordiga, Edder Garcia, Gerhard D. Pirngruber, Martin Vreeke, Leszek Gora, Synthesis and crystal chemistry of the STA-12 family of metal N,N′-piperazinebis(methylenephosphonate)s and applications of STA-12(Ni) in the separation of gases Microporous and Mesoporous Materials. ,vol. 157, pp. 3- 17 ,(2012) , 10.1016/J.MICROMESO.2011.12.003
Jian-Rong Li, Yuguang Ma, M Colin McCarthy, Julian Sculley, Jiamei Yu, Hae-Kwon Jeong, Perla B Balbuena, Hong-Cai Zhou, None, Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks Coordination Chemistry Reviews. ,vol. 255, pp. 1791- 1823 ,(2011) , 10.1016/J.CCR.2011.02.012
Zhenxia Chen, Shengchang Xiang, Hadi D. Arman, Jalal U. Mondal, Peng Li, Dongyuan Zhao, Banglin Chen, Three-Dimensional Pillar-Layered Copper(II) Metal−Organic Framework with Immobilized Functional OH Groups on Pore Surfaces for Highly Selective CO2/CH4 and C2H2/CH4 Gas Sorption at Room Temperature Inorganic Chemistry. ,vol. 50, pp. 3442- 3446 ,(2011) , 10.1021/IC102347B
Kevin J. Gagnon, Houston P. Perry, Abraham Clearfield, Conventional and unconventional metal-organic frameworks based on phosphonate ligands: MOFs and UMOFs. Chemical Reviews. ,vol. 112, pp. 1034- 1054 ,(2012) , 10.1021/CR2002257
Liyuan Deng, May-Britt Hägg, Techno-economic evaluation of biogas upgrading process using CO2 facilitated transport membrane International Journal of Greenhouse Gas Control. ,vol. 4, pp. 638- 646 ,(2010) , 10.1016/J.IJGGC.2009.12.013
Evan J. Granite, Henry W. Pennline, Photochemical Removal of Mercury from Flue Gas Industrial & Engineering Chemistry Research. ,vol. 41, pp. 5470- 5476 ,(2002) , 10.1021/IE020251B