Synthesis of nanostructured bio-related materials by hybridization of synthetic polymers with polysaccharides or saccharide residues.

摘要: In the first part of this review, we describe synthesis nanostructured hybrid materials composed polysaccharides and synthetic polymers. Amylose-synthetic polymer inclusion complexes were synthesized by amylose-forming polymerization using phosphorylase enzyme in presence polymers such as polyethers polyesters. Alginate-polymethacrylate prepared free-radical cationic methacrylate sodium alginate. These methods allow simultaneous control nanostructure with polymerization, giving well-defined materials. second novel glycopolymers rigid structures. Polyaniline-based means oxidative N-glycosylaniline. Polysiloxane-based introduction sugar-lactone to rodlike polysiloxane. had regular higher-ordered structures due their backbones, resulting three-dimensional array sugar-residues.