Design of Supramolecular Cyclodextrin Complex Sensors for Ion and Molecule Recognition in Water
作者： Takashi Hayashita , Akiyo Yamauchi , Ai-Jun Tong , Jong Chan Lee , Bradley D. Smith
DOI: 10.1007/S10847-003-8845-5
关键词: Supramolecular chemistry 、 Crown ether 、 Pyrene 、 Inorganic chemistry 、 Boronic acid 、 Alkali metal ion binding 、 Chemistry 、 Cyclodextrin 、 Combinatorial chemistry 、 Phenylboronic acid 、 Photoinduced electron transfer
摘要: The design and function of novel supramolecular fluoroionophore/cyclodextrin (CyD) complex sensors for ion molecule recognition in water are reviewed. For the crown ether fluoroionophore/c-CyD complex, dimerization fluoroionophore inside c-CyD is found to be selectively promoted by alkali metal binding, thereby resulting metal-ion-selective pyrene dimer emission water. This successfully utilized a podand sensing toxic lead boronic acid fluoroionophore/b-CyD binds sugars produces increased fluorescence response mechanism appears due suppression photoinduced electron transfer (PET) from donor trigonal phenylboronic acceptor. provided
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