Phenylboronic acid-catalyzed tandem construction of S–S and C–S bonds: a new method for the synthesis of benzyl disulfanylsulfone derivatives from S-benzyl thiosulfonates
作者： Raju Jannapu Reddy , Md. Waheed , Gamidi Rama Krishna
DOI: 10.1039/D0OB00442A
关键词: Phenylboronic acid 、 Catalysis 、 Chemistry 、 Tandem 、 Combinatorial chemistry
摘要: A unique phenylboronic acid-catalyzed dimerization–sulfonylation of S-benzyl thiosulfonates has been disclosed. metal-free tandem construction S–S and C–S bonds is an operationally simple method to access a wide range benzyl disulfanylsulfone derivatives in high excellent yields. Moreover, the robustness this transformation demonstrated by gram-scale reactions, plausible mechanism also proposed.
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