Transient spontaneous Raman observation of the reaction dynamics of triplet quinoxaline in aqueous solution
作者： S. M. Beck , L. E. Brus
DOI: 10.1063/1.441933
关键词: Reaction dynamics 、 Raman spectroscopy 、 Deuterium 、 Aqueous solution 、 Protonation 、 Photochemistry 、 Diazanaphthalene 、 Quinoxaline 、 Chemistry 、 Ultrafast laser spectroscopy
摘要: A sensitive apparatus for transient spontaneous Raman studies of reactions in solution is described. The involves two Nd:YAG lasers coupled with multichannel, low noise spectral detection. technique applied to the chemistry aqueous triplet quinoxaline (1,4‐diazanaphthalene). spectra exhibit a sequence previously unobserved protonation reactions, showing be more complex than appeared earlier absorption studies. are acidic deuterium substitution protonated T1H+, and (apparently) diprotonated T1H2++.
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