Picosecond relaxation processes in excited state quinoxaline
作者： Robert W. Anderson , Donald E. Damschen , Gary W. Scott , Larry D. Talley
DOI: 10.1063/1.438458
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摘要: Excited state absorption spectra of quinoxaline in benzene, isooctane, and cis‐1,3‐pentadiene at 7 130 ps after excitation are reported. Picosecond kinetics 422 533 nm also In the nonaromatic solvents, bands ∼425 (Sn←S1 Tn←T1) ∼ 530 (mostly Sn←S1) observed transient spectra. Decay ∼530‐nm band gives k−1isc?23 solvents. benzene solvent, excited more complex, decay longer, quinoxaline–benzene exciplex formation is suggested.
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