Mechanistic Insights into Oxidative Oligomerization of p-Phenylenediamine and Resorcinol
作者： Aaron D. Bailey , Bryan P. Murphy , Hairong Guan
关键词: Oxidative phosphorylation 、 Dye molecule 、 Reactive intermediate 、 Resorcinol 、 Polymer chemistry 、 Oxidative coupling of methane 、 Photochemistry 、 Chemistry 、 Reactivity (chemistry) 、 p-Phenylenediamine 、 Reagent
摘要: An efficient synthesis of a green dye from oxidative coupling p-phenylenediamine (PPD) and resorcinol (in 2:1 ratio) has been developed. Reactivity studies this molecule with variety reagents (PPD, resorcinol, the oxidized form itself, dinuclear indo dye) demonstrate that it cannot be key reactive intermediate in reported oligomerization PPD resorcinol. However, trinuclear species does large aggregates. At least one viable pathway demonstrated dye.
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