Mechanism of skeletal reactions of hydrocarbon on metals

作者: E.H. Van Broekhoven , V. Ponec

DOI: 10.1016/0079-6816(85)90016-4

关键词: SelectivityHydrocarbonChemical bondMechanism (sociology)Particle sizeChemistryMetalCatalysisComputational chemistryInorganic chemistryReaction mechanism

摘要: Abstract The mechanism and intermediates of the title reaction are described. subjects discussed include influence carbonaceous layers, particle size, alloying etc., on activity selectivity metals. roles chemical bond strengths metal-carbon multiple bonds also briefly discussed. Discussion metals reviews well established data theories concerning skeletal reactions.

参考文章(136)
Gabor A. Somorjai, Chemistry in Two Dimensions: Surfaces ,(1981)
G. C. Bond, Catalysis By Metals ,(1962)
Robert Thomas Sanderson, Chemical Bonds and Bond Energy ,(1976)
C. Apesteguia, J. Barbier, Sulfuration of Pt/Al2O3, Pt−Re/Al2O3 and Pt−Ir/Al2O3 catalysts Reaction Kinetics and Catalysis Letters. ,vol. 19, pp. 351- 354 ,(1982) , 10.1007/BF02074060
G. A. Mills, Heinz Heinemann, T. H. Milliken, A. G. Oblad, Houdriforming Reactions) Catalytic Mechanism Industrial & Engineering Chemistry. ,vol. 45, pp. 134- 137 ,(1953) , 10.1021/IE50517A043