Styrene/Acrylonitrile Graft Natural Rubber as Compatibilizer in Rubber Blends
作者： Siriya Angnanon , Pattarapan Prasassarakich , Napida Hinchiranan
DOI: 10.1080/03602559.2011.574667
关键词: Composite material 、 Natural rubber 、 Nitrile rubber 、 Benzoyl peroxide 、 Styrene 、 Materials science 、 Copolymer 、 Ultimate tensile strength 、 Acrylonitrile 、 Compatibilization
摘要: A graft copolymer of acrylonitrile (ACN) and styrene (ST) on natural rubber (NR) was prepared by solution polymerization initiated benzoyl peroxide. The effect NR (GNR) applied as a compatibilizer for NR/nitrile (NBR) blends their mechanical physical properties investigated. results revealed that the tensile oil-swelling resistance increased with increasing %graft GNR. fracture surfaces compatibilized NR/NBR vulcanizates attested scanning electron microscopy indicated improvement interfacial adhesion between two phases. Moreover, dynamic were also reported.
researchgate.net 
sci-hub.se 参考文章(26)
Darvishi, M T Taghi Zadeh, Kinetics and Mechanism of Heterogeneous Graft Polymerization of Acrylonitrile onto Polyvinyl Alcohol Initiated with Ceric Ammonium Nitrate IRANIAN POLYMER JOURNAL (ENGLISH). ,vol. 10, pp. 283- 292 ,(2001)
Michael V. Lewan, NR/NBR blends - basic problems and solutions Springer, Dordrecht. pp. 53- 67 ,(1998) , 10.1007/978-94-011-4922-8_5
Yu-hui Ao, Kai Tang, Na Xu, Hai-dong Yang, Hui-xuan Zhang, Compatibilization of PP/SEBS-MAH blends by grafting Glycidyl Methacrylate onto Polypropylene Polymer Bulletin. ,vol. 59, pp. 279- 288 ,(2007) , 10.1007/S00289-007-0764-Y
Mircea Teodorescu, Mihai Dimonie, Constantin Draghici, Sever Şerban, Gabriel Vasilievici, Mirela Coleşa, Grafting styrene onto poly(vinyl acetate) by free radical chain transfer reactions Reactive & Functional Polymers. ,vol. 61, pp. 387- 395 ,(2004) , 10.1016/J.REACTFUNCTPOLYM.2004.08.001
P. PRASASSARAKICH, P. SINTOORAHAT, N. WONGWISETSIRIKUL, Enhanced Graft Copolymerization of Styrene and Acrylonitrile onto Natural Rubber Journal of Chemical Engineering of Japan. ,vol. 34, pp. 249- 253 ,(2001) , 10.1252/JCEJ.34.249
Chen-Ming Chen, Tsung-Eong Hsieh, Mark O. Liu, Preparation of epoxy-modified polyethylene by graft extrusion and its applications to polyphenylene sulfide alloys as a compatibilizer Reactive & Functional Polymers. ,vol. 68, pp. 1307- 1313 ,(2008) , 10.1016/J.REACTFUNCTPOLYM.2008.06.008
N. Hinchiranan, B. Suppaibulsuk, S. Promprayoon, P. Prasassarakich, Improving properties of modified acrylic sheet via addition of graft natural rubber Materials Letters. ,vol. 61, pp. 3951- 3955 ,(2007) , 10.1016/J.MATLET.2006.12.069
Guo-Hua Hu, Herv� Cartier, Styrene‐assisted melt free radical grafting of glycidyl methacrylate onto an ethylene and propylene rubber Journal of Applied Polymer Science. ,vol. 71, pp. 125- 133 ,(1999) , 10.1002/(SICI)1097-4628(19990103)71:1<125::AID-APP15>3.0.CO;2-S
A. S. Brar, S. K. Hekmatyar, Microstructure determination of the acrylonitrile-styrene-methyl methacrylate terpolymers by NMR spectroscopy Journal of Applied Polymer Science. ,vol. 74, pp. 3026- 3032 ,(1999) , 10.1002/(SICI)1097-4628(19991220)74:13<3026::AID-APP3>3.0.CO;2-C
Zhiping Zeng, Lianshi Wang, Tongmin Cai, Xiangbin Zeng, Synthesis of high rubber styrene–EPDM–acrylonitrile graft copolymer and its toughening effect on SAN Journal of Applied Polymer Science. ,vol. 94, pp. 416- 423 ,(2004) , 10.1002/APP.20579