作者: Jens Schneider , Sabine Begand , Ralf Kriegel , Christian Kaps , Wilfried Glien
DOI: 10.1111/J.1551-2916.2008.02700.X
关键词: Monoclinic crystal system 、 Surface roughness 、 Phase (matter) 、 Arrhenius plot 、 Rietveld refinement 、 Isothermal transformation diagram 、 Materials science 、 Analytical chemistry 、 Cubic zirconia 、 Activation energy 、 Mineralogy
摘要: The corrosion of alumina-toughened zirconia (ATZ) as a consequence hydrothermal treatment was investigated, especially the transformation kinetics from tetragonal to monoclinic phase. For this purpose, polished ATZ specimens (R <5 nm) were aged in water vapor at different temperatures ranging 70° 134°C. fraction phase determined using X-ray diffraction and Rietveld refinement. isothermal curves obtained fitted Mehl-Johnson-Avrami equation by least squares. An Arrhenius plot rates used determine activation energy pre-exponential factor. Following procedure, kinetic parameters extrapolated down body temperature formation simulated. In addition, optical interferometry on well-polished < 2 alternatively calculate histogram dataset. results agree very well with those measurements. Additionally, development surface roughness increasing aging time is discussed.