Introduction of metal precursors by electrodeposition for the in situ growth of metal–organic framework membranes on porous metal substrates

作者: Sheng Zhou , Yanying Wei , Libin Zhuang , Liang-Xin Ding , Haihui Wang

DOI: 10.1039/C6TA09469D

关键词: Materials scienceMetal-organic frameworkMetalReactivity (chemistry)NanotechnologyPorosityIn situPorous metalMembrane

摘要: We report here a facile and efficient electrodeposition method to modify inexpensive porous stainless-steel nets for use as substrates in the in situ growth of metal–organic framework membranes, such as ZIF-8, ZIF-67 and HKUST-1. Using this method, different metal precursors can be electrodeposited depending on the central metals required in the target metal–organic frameworks. The inorganic modifiers prepared by this approach are sufficiently reactive for the one-step growth of continuous metal–organic framework …

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