Densification behavior and properties of alumina–chrome ceramics: Effect of TiO2

作者: Mithun Nath , Sandipan Sen , K. Banerjee , A. Ghosh , H.S. Tripathi

DOI: 10.1016/J.CERAMINT.2012.06.013

关键词: CeramicMetallurgyCorrosionMaterials scienceFlexural strengthMicrostructureSinteringAtmospheric temperature rangeReducing atmospherePorosity

摘要: Abstract Highly dense alumina–chrome bodies with low porosity are usually used as corrosion and thermal resistant refractories. Alumina–chrome refractory molar ratio 1:1 was developed using chemical grade hydrated alumina chromium (III) oxide by conventional sintering route. Batch materials were attrition milled, isostatically pressed sintered in the temperature range from 1000 °C to 1700 °C 2 h soaking at peak temperature. Phase development of studied X-ray diffraction. Sintering temperature, condition addition aid (TiO 2 ) have immense effect on densification refractory. almost nil apparent 1500 °C reducing atmosphere. Flexural strength room 1200 °C also measured. 1 wt% TiO gives optimum result respect flexural strength.

参考文章(18)
Seung-Am Cho, F.J. Arenas, J. Ochoa, Densification and hardness of Al2O3Cr2O3 system with and without Ti addition Ceramics International. ,vol. 16, pp. 301- 309 ,(1990) , 10.1016/0272-8842(90)90044-G
A. G. Tarasov, V. A. Gorshkov, V. I. Yukhvid, Phase composition and microstructure of Al2O3-Cr2O3 solid solutions prepared by self-propagating high-temperature synthesis Inorganic Materials. ,vol. 43, pp. 724- 728 ,(2007) , 10.1134/S0020168507070102
Takehiko Hirata, Tatsuo Morimoto, Satoshi Ohta, Nozomu Uchida, Improvement of the corrosion resistance of alumina–chromia ceramic materials in molten slag Journal of The European Ceramic Society. ,vol. 23, pp. 2089- 2096 ,(2003) , 10.1016/S0955-2219(03)00023-2
K. Shibata, M. Yoshinaka, K. Hirota, O. Yamaguchi, Fabrication and mechanical properties of Cr2O3 solid solution ceramics in the system Cr2O3-Al2O3 Materials Research Bulletin. ,vol. 32, pp. 627- 632 ,(1997) , 10.1016/S0025-5408(97)00015-9
H. G. Emblem, T. J. Davies, A. Harabi, A. A. Ogwu, C. S. Nwobodo, V. Tsantzalou, Solid-state chemistry of alumina-chrome refractories Journal of Materials Science Letters. ,vol. 11, pp. 820- 821 ,(1992) , 10.1007/BF00730475
Takehiko Hirata, Katsunori Akiyama, Hirokazu Yamamoto, Sintering behavior of Cr2O3–Al2O3 ceramics Journal of The European Ceramic Society. ,vol. 20, pp. 195- 199 ,(2000) , 10.1016/S0955-2219(99)00161-2
Hao-Tung Lin, Bo-Zon Liu, Wei-hsio Chen, Jow-Lay Huang, Pramoda K Nayak, None, Study of color change and microstructure development of Al2O3–Cr2O3/Cr3C2 nanocomposites prepared by spark plasma sintering Ceramics International. ,vol. 37, pp. 2081- 2087 ,(2011) , 10.1016/J.CERAMINT.2011.02.018
Doh-Hyung Riu, Young-Min Kong, Hyoun-Ee Kim, Effect of Cr2O3 addition on microstructural evolution and mechanical properties of Al2O3 Journal of The European Ceramic Society. ,vol. 20, pp. 1475- 1481 ,(2000) , 10.1016/S0955-2219(00)00023-6
Federica Bondioli, Anna Maria Ferrari, Cristina Leonelli, Tiziano Manfredini, Laura Linati, Piercarlo Mustarelli, Reaction Mechanism in Alumina/Chromia (Al2O3-Cr2O3) Solid Solutions Obtained by Coprecipitation Journal of the American Ceramic Society. ,vol. 83, pp. 2036- 2040 ,(2004) , 10.1111/J.1151-2916.2000.TB01508.X