Isotopic and vibronic coupling effects in the valence electron spectra of H2 16O, H2 18O, and D2 16O
作者： L. Karlsson , L. Mattsson , R. Jadrny , R. G. Albridge , S. Pinchas
DOI: 10.1063/1.430423
关键词: Excited state 、 Photoionization 、 Atomic physics 、 Ion 、 Vibronic coupling 、 Chemistry 、 Valence electron 、 Ionization energy 、 Spectral line 、 Isotopic shift
摘要: Isotopic shift data for Hei induced high resolution valence electron spectra of H2 16O, H2 18O, and D2 16O are presented. From the differences in vibrational subspectra we were able to deduce adiabatic ionization energies geometries ions assign excited vibrations normal modes. The ν2 progression 2A1 band was found be affected by strong vibronic coupling.
harvard.edu
scitation.org
aip.org 
sci-hub.se 参考文章(19)
J. W. C. Johns, ON THE ABSORPTION SPECTRUM OF H2O AND D2O IN THE VACUUM ULTRAVIOLET Canadian Journal of Physics. ,vol. 41, pp. 209- 219 ,(1963) , 10.1139/P63-027
R.N. Dixon, G. Duxbury, M. Horani, J. Rostas, The H2S+ radical ion Molecular Physics. ,vol. 22, pp. 977- 992 ,(1971) , 10.1080/00268977100103311
Photoelectron Spectra and Valence Shell Orbital Structures of Groups V and VI Hydrides Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 326, pp. 181- 197 ,(1972) , 10.1098/RSPA.1972.0004
Gerhard Herzberg, Bryce L. Crawford, Infrared and Raman spectra of polyatomic molecules The Journal of Physical Chemistry. ,vol. 50, pp. 288- 288 ,(1946) , 10.1021/J150447A021
T. Bergmark, L. Karlsson, R. Jadrny, L. Mattsson, R.G. Albridge, K. Siegbahn, Isotopic effects in the electron spectra of H2 16O, H2 18O, and D2 16O Journal of Electron Spectroscopy and Related Phenomena. ,vol. 4, pp. 85- 89 ,(1974) , 10.1016/0368-2048(74)80047-2
L.S. Cederbaum, W. Domcke, An analogue to koopmans' theorem for the problem of vibrational structure in electron detachment spectra Chemical Physics Letters. ,vol. 25, pp. 357- 363 ,(1974) , 10.1016/0009-2614(74)85317-0
W. S. Benedict, N. Gailar, Earle K. Plyler, Rotation‐Vibration Spectra of Deuterated Water Vapor The Journal of Chemical Physics. ,vol. 24, pp. 1139- 1165 ,(1956) , 10.1063/1.1742731
High resolution molecular photoelectron spectroscopy II. Water and deuterium oxide Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 307, pp. 27- 36 ,(1968) , 10.1098/RSPA.1968.0172
J.C. Leclerc, J.A. Horsley, J.C. Lorquet, Excited states of gaseous ions. IV. Potential energy surfaces of the H2O+ ion Chemical Physics. ,vol. 4, pp. 337- 352 ,(1974) , 10.1016/0301-0104(74)85002-0
S. Bell, The spectra of H2O and D2O in the vacuum ultraviolet Journal of Molecular Spectroscopy. ,vol. 16, pp. 205- 213 ,(1965) , 10.1016/0022-2852(65)90098-6