A theoretical adaptation of the classical isotope dilution technique for practical routine analytical determinations by means of inductively coupled plasma mass spectrometry
作者： Huub Klinkenberg , Werner Van Borm , Frans Souren
DOI: 10.1016/0584-8547(95)01386-5
关键词: Chemistry 、 Mass spectrometry 、 Analytical chemistry 、 Sensitivity (control systems) 、 Standard curve 、 Calibration curve 、 Detection limit 、 Isotope dilution 、 Inductively coupled plasma mass spectrometry 、 Calibration
摘要: The classical isotope dilution approach is adapted for routine element determinations by inductively coupled plasma mass spectrometry (ICP-MS). In the described a calibration graph, which curved definition, used as reference. This graph can be derived both theoretically and practically measuring known concentrations. It shown that deliberately introduced instrumental sensitivity changes are completely corrected for. analytical consequences in terms of curvature blank detection limits discussed.
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P.J. De Bièvre, G.H. Debus, Precision mass spectrometric isotope dilution analysis Nuclear Instruments and Methods. ,vol. 32, pp. 224- 228 ,(1965) , 10.1016/0029-554X(65)90516-1
P. De Bièvre, I.L. Barnes, Table of the isotopic composition of the elements as determined by mass spectrometry International Journal of Mass Spectrometry and Ion Processes. ,vol. 65, pp. 211- 230 ,(1985) , 10.1016/0168-1176(85)85065-5
Joseph J. Thompson, R. S. Houk, A Study of Internal Standardization in Inductively Coupled Plasma-Mass Spectrometry: Applied Spectroscopy. ,vol. 41, pp. 801- 806 ,(1987) , 10.1366/0003702874448265
Scott D. Tanner, Space charge in ICP-MS: calculation and implications Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 47, pp. 809- 823 ,(1992) , 10.1016/0584-8547(92)80076-S
John R. Garbarino, Howard E. Taylor, Stable isotope dilution analysis of hydrologic samples by inductively coupled plasma mass spectrometry Analytical Chemistry. ,vol. 59, pp. 1568- 1575 ,(1987) , 10.1021/AC00138A018
J.C. Miller, P.J. Worsfold, J.N. Miller, Statistics for Analytical Chemistry ,(1993)
C. Vandecasteele, M. Nagels, H. Vanhoe, R. Dams, Suppression of analyte signal in inductively-coupled plasma/mass spectrometry and the use of an internal standard Analytica Chimica Acta. ,vol. 211, pp. 91- 98 ,(1988) , 10.1016/S0003-2670(00)83671-5
R. S. Houk, Mass spectrometry of inductively coupled plasmas Analytical Chemistry. ,vol. 58, ,(1986) , 10.1021/AC00292A003
Auke A. van Heuzen, Tjeerd Hoekstra, Bob van Wingerden, Precision and accuracy attainable with isotope dilution analysis applied to inductively coupled plasma mass spectrometry: theory and experiments Journal of Analytical Atomic Spectrometry. ,vol. 4, pp. 483- 489 ,(1989) , 10.1039/JA9890400483
Frank Vanhaecke, Hans Vanhoe, Richard Dams, Carlo Vandecasteele, The use of internal standards in ICP-MS. Talanta. ,vol. 39, pp. 737- 742 ,(1992) , 10.1016/0039-9140(92)80088-U