Synthèse électrochimique du cycle époxydique. Communication préliminaire
作者： Raymond Gerdil
关键词: Epoxy 、 Reductive cleavage 、 Intramolecular force 、 Inorganic chemistry 、 Electrolysis 、 Cathode 、 Electrode 、 Organic chemistry 、 Chemistry 、 Mercury (element) 、 Polarography
摘要: The polarographic behaviour of ditosyloxy alkanes TsO(CH2)nOTs in aprotic medium suggests that intramolecular cyclisation takes place after reductive cleavage a single SO2O bond at the dropping electrode. This hypothesis was verified by controlled potential electrolysis lower homologues mercury cathode. High yields epoxy compounds are obtained this method.
sci-hub.se 参考文章(1)
Parviz Yousefzadeh, Charles K. Mann, Electrochemical reduction of alkyl esters of p-toluenesulfonic acid Journal of Organic Chemistry. ,vol. 33, pp. 2716- 2720 ,(1968) , 10.1021/JO01271A022